Highly enantioselective synthesis of silahelicenes using Ir-catalyzed [2+2+2] cycloaddition.
نویسندگان
چکیده
Silahelicenes, which contain two silole moieties in a helically chiral structure, were synthesized by a chiral Ir-catalyzed intermolecular [2+2+2] cycloaddition of tetraynes with diynes along with a Ni-mediated intramolecular [2+2+2] cycloaddition. The photophysical properties of the obtained highly enantiomerically enriched silahelicenes (up to 93% ee) were also measured.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 9 شماره
صفحات -
تاریخ انتشار 2012